Construction Additives
GEOCON · Set Retarder & Workability Control

SODIUM GLUCONATE
FOR CONCRETE, GROUT & CEMENTITIOUS SYSTEMS

High-purity sodium gluconate for controlled cement hydration, extended setting time and workability retention. Designed for formulation screening in ready-mix concrete, mass concrete, precast, grout, repair mortar and selected dry-mix systems.

Chemistry: Sodium D-Gluconate CAS No.: 527-07-1 Molecular Weight: 218.14 g/mol pH · 10% Solution: 6.2–7.8
≥99% Typical technical-grade assay target
≤0.5% Typical maximum loss on drying
59 g Approx. water solubility per 100 mL at 25°C
218.14 Molecular weight, g/mol
360° Matrix-to-surface approach
Graphical View

HOW SODIUM
GLUCONATE CONTROLS HYDRATION

The dominant practical result is a longer induction period before rapid cement hydration. The exact molecular pathway depends on the cement system.

FROM DOSING TO CONTROLLED SET

Sodium gluconate interacts with the cement hydration environment and delays the rapid hydration of silicate phases, especially C₃S. This extends the induction period and can preserve workability for longer.

01

Dissolve & disperse

Gluconate distributes through the mix water and cement paste.

02

Interact with hydration sites / ions

The gluconate anion influences dissolution and hydration reactions in the cement system.

03

Extend induction period

Rapid silicate hydration is delayed, slowing the onset of set.

04

Longer placement window

Concrete or mortar can retain workability for an extended period when properly dosed.

SODIUM
GLUCONATE

C₆H₁₁NaO₇

CEMENT + WATER

Hydration environment

C₃S / C₃A / Ca²⁺

LONGER
INDUCTION
PERIOD

HYDRATION PROGRESS
WITH GLUCONATE CONTROL TIME →

Sodium gluconate hydration-control concept

Conceptual hydration profile for communication only. Actual heat release, set time and strength development depend on cement composition, temperature, water/binder ratio and dosage.

Construction Applications

Where Sodium Gluconate Earns Its Place

Most applications use sodium gluconate as one component of a broader admixture system rather than as a stand-alone finished admixture.

01 · Ready-mix

Workability Retention

Screen where transport time, traffic, pumping or hot-weather placement demands a longer workable window.

02 · Mass concrete

Controlled Setting

Useful when slower hydration and extended placement sequencing are required for large pours.

03 · Precast

Fine-Tuned Set Control

Can be used at carefully controlled low dosage where precise set adjustment is required without chloride acceleration.

04 · Grout

Placement Window

Supports fluidity retention and delayed stiffening in compatible cementitious grout formulations.

05 · Dry mix

Retardation Balance

Can be evaluated in selected mortars and repair systems where open time and workable life need extension.

06 · PCE blends

Admixture Formulation

Frequently screened alongside polycarboxylate, SNF or lignosulfonate systems; compatibility and set response must be checked.

Application environment

FROM ADMIXTURE LAB TO CONCRETE PLACEMENT

Ready-mix concrete truck transporting formulated concrete

Ready-Mix & Transport Control

Sodium gluconate can help extend the workable period where concrete must remain pumpable and placeable through transport and site delays.

High-rise concrete pumping and placement

Laboratory Qualification

Run set-time, slump-retention and strength trials in the actual cement/admixture system.

Wet-mix shotcrete application on reinforced surface

Mortar & Grout Systems

Evaluate open time, consistency, set and early strength together.

Technical Data

Full
Specification

Typical technical-grade specification for construction use.

Important: These values are presented as a technical-grade reference specification. The order-specific Certificate of Analysis and agreed sales specification should prevail for each supplied batch.

Parameter Typical Specification
Product Sodium Gluconate · Technical Grade
Chemical Name Sodium D-Gluconate
CAS No. 527-07-1
EC No. 208-407-7
Molecular Formula C₆H₁₁NaO₇
Molecular Weight 218.14 g/mol
Appearance White to slightly yellowish crystalline powder
Assay / Purity ≥ 99.0%
pH · 10% aqueous solution 6.2 – 7.8
Loss on Drying ≤ 0.50%
Reducing Substances ≤ 0.70%
Chloride, as Cl ≤ 0.07%
Sulfate, as SO₄ ≤ 0.05%
Heavy Metals ≤ 10 mg/kg
Lead, Pb ≤ 2 mg/kg
Arsenic, As ≤ 2 mg/kg
Solution Clarity Clear / cloudless
Water Solubility Very soluble in water
Physical Density Approx. 1.8 g/cm³ · reference property
Primary Construction Function Cement set retarder / hydration-control raw material
Reference Performance Graph

DOSAGE CHANGES THE SET WINDOW

Illustrative sodium gluconate dosage vs. additional set delay

Reference example for one Portland-cement system. This is not a universal performance curve; temperature, cement chemistry, w/c ratio and other admixtures can substantially alter the result.

20 h 16 12 8 4 0 0.05% 0.10% 0.15% 0.20% 0.30% SODIUM GLUCONATE · % BY CEMENT WEIGHT
Beginning of set · reference delay
End of set · reference delay
Dosage Sensitivity

SMALL CHANGES CAN CREATE LARGE SET-TIME CHANGES.

Sodium gluconate can become strongly retarding as dosage increases. Avoid moving directly from a low trial to a high dosage without intermediate testing.

  • Use the same dosage basis in every trial: cement weight or total binder weight.
  • Test at the actual concrete temperature—not only at laboratory room temperature.
  • Record initial/final set, slump retention and 1-day strength together.
  • Re-qualify when cement source or admixture package changes.
FORMULATION TOOL

DOSAGE
CALCULATOR

Convert a dry sodium gluconate dosage percentage into kilograms required for your binder batch. Use this only as a trial-planning tool.

DRY SODIUM GLUCONATE
0.72 kg
EQUIVALENT PER 100 KG BINDER
90 g

Formula: binder weight × dosage % ÷ 100. Actual optimum dosage must be determined by laboratory trials.

RECOMMENDED LABORATORY APPROACH

QUALIFY THE
DOSAGE

Start with a small, controlled trial matrix rather than a single dosage.

0.03%

Low starting screen

0.05%

Moderate screen

0.08%

Stronger retardation screen

0.10%

High screen · watch over-retardation

Initial & final set

Use a consistent method and test at the intended placement temperature.

Slump / flow retention

Record initial value and time-based retention at relevant intervals.

1-day strength

Check early-strength penalty when the set window is extended.

7 & 28-day strength

Confirm that retardation does not compromise the required final performance.

Bleeding / segregation

Observe the full mixture; workability gain must not create instability.

Admixture compatibility

Repeat trials with the intended PCE, SNF, lignosulfonate or other package.

Formulation Compatibility

CHECK THE COMPLETE ADMIXTURE SYSTEM

Sodium gluconate rarely works in isolation. Sequence of addition, superplasticizer chemistry and cement source can change the response.

PCE Superplasticizers

Often combined for slump retention and controlled set. Check for excessive retardation and strength delay.

SNF / Melamine

Can be screened in conventional water-reducing systems; test fluidity, set and air content.

Lignosulfonates

Both chemistries can retard set, so combined dosage may require significant reduction.

SCMs & Cement Source

Fly ash, slag, silica fume, sulfate balance and clinker mineralogy can shift dosage response.

Packaging, Storage & Handling

KEEP THE POWDER DRY & CONTROLLED

Packaging

Common technical-grade supply is in 25 kg moisture-resistant bags. Confirm the order-specific pack and pallet configuration.

Storage

Store sealed in a cool, dry area away from direct moisture and damaged packaging.

Handling

Avoid unnecessary dust generation. Use normal industrial hygiene and the precautions stated in the current SDS.

Shelf Life

Use the shelf-life statement on the supplied TDS/COA and keep product protected from moisture during storage.

Technical questions

FAQ

Practical questions for formulators working with sodium gluconate in cementitious systems.

What is the main function of sodium gluconate in concrete?
It is primarily used as a hydration-control and set-retarding raw material. It can also contribute to workability retention and water-reduction behaviour depending on the complete admixture system.
What dosage should be used?
There is no universal dosage. A controlled screening matrix around approximately 0.03–0.10% by cement or binder weight is useful for development work, followed by optimization under the actual cement, temperature and admixture conditions.
Can too much sodium gluconate stop or severely delay set?
Yes. The chemistry is highly dosage-sensitive. Overdosage can produce very long set delays and low early strength, so incremental trials are essential.
Is sodium gluconate suitable for hot-weather concrete?
It is commonly evaluated where higher temperature accelerates hydration and a longer transport or placement window is required. Trial mixes should be run at realistic concrete temperatures.
Can it be blended with PCE superplasticizer?
Yes, it is frequently screened as part of PCE-based admixture systems, but compatibility, set delay, slump retention and strength should be verified for the exact formulation.
Does sodium gluconate improve strength?
Strength response is dosage- and system-dependent. Published cement studies show that low dosages can affect early and later strength differently. Never use strength assumptions without actual testing.
Does cement source matter?
Yes. C₃S/C₃A content, sulfate balance, fineness, SCMs and alkali content can change the retardation response substantially.
How should a liquid admixture containing sodium gluconate be calculated?
Convert the desired dry sodium gluconate mass into solution mass using the active-solids percentage of the liquid formulation. Keep the basis consistent throughout testing.
What should be checked on the COA?
Assay, loss on drying, pH, reducing substances, chloride, sulfate and relevant trace-metal limits should match the agreed purchase specification.
Can GEOCON support application qualification?
Yes. Share the cement/binder system, admixture package, target set time, temperature, slump-retention requirement and strength targets so an appropriate screening plan can be prepared.

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